THE POTENTIAL OF CNT-PVA MEMBRANE AS A GREEN TECHNOLOGY ALTERNATIVE
DOI:
https://doi.org/10.47701/0g320j79Keywords:
Carbon Nanotube, Polyvinyl Alcohol, Green Technology, Sustainable MaterialsAbstract
The development of advanced membrane technologies is essential for addressing environmental challenges, particularly in wastewater treatment and oil-water separation. Polyvinyl alcohol (PVA) is a hydrophilic, environmentally friendly polymer commonly used for membrane fabrication; however, it suffers from high swelling and low mechanical strength, which limits its long-term performance. To overcome these drawbacks, carbon nanotubes (CNTs) were incorporated into the PVA matrix to form PVA-CNT composite membranes. CNTs serve as structural reinforcements, enhancing mechanical strength, thermal stability, and inter-chain bonding within the PVA network. The interconnected pore structure and high conductivity of CNTs also improve membrane selectivity and reduce swelling by stabilizing the polymer structure when exposed to water or aqueous solutions. Additionally, the modified surface properties provided by CNTs result in superior fouling resistance, minimizing pore blockage and maintaining water flux over extended operation periods. This study demonstrates that PVA-CNT composite membranes offer a sustainable and energy-efficient solution for separation processes, making them highly suitable for oil-water separation, industrial wastewater treatment, and other filtration applications such as water purification and organic compound removal. The findings highlight the potential of PVA-CNT membranes as a green technology that combines high performance with environmental sustainability. PVA-CNT membranes offer a promising approach for developing next-generation membranes with optimized structural and functional properties for environmental applications.
References
Basiuk, E. V., Anis, A., Bandyopadhyay, S., Alvarez-Zauco, E., Chan, S. L. I., & Basiuk, V. A. (2009). Poly(vinyl alcohol)/CNT composites: An effect of cross-linking with glutaraldehyde. Superlattices and Microstructures, 46(1–2), 379–383. https://doi.org/10.1016/j.spmi.2008.10.007
Choo, K., Ching, Y. C., Chuah, C. H., Julai, S., & Liou, N. S. (2016). Preparation and characterization of polyvinyl alcohol-chitosan composite films reinforced with cellulose nanofiber. Materials, 9(8), 1–16. https://doi.org/10.3390/ma9080644
Dudchenko, A. V., Rolf, J., Russell, K., Duan, W., & Jassby, D. (2014). Organic fouling inhibition on electrically conducting carbon nanotube-polyvinyl alcohol composite ultrafiltration membranes. Journal of Membrane Science, 468, 1–10. https://doi.org/10.1016/j.memsci.2014.05.041
Huang, J., Ran, X., Sun, L., Bi, H., & Wu, X. (2024). Recent advances in membrane technologies applied in oil–water separation. Discover Nano, 19(1). https://doi.org/10.1186/s11671-024-04012-w
Parangusan, H., Ponnamma, D., Hassan, M. K., Adham, S., & Al-Maadeed, M. A. A. (2019). Designing carbon nanotube-based oil absorbing membranes from gamma irradiated and electrospun polystyrene nanocomposites. Materials, 12(5). https://doi.org/10.3390/ma12050709
Shah, S. A., Ali, H., Inayat, M. I., E. Mahmoud, E., AL Garalleh, H., & Ahmad, B. (2024). Effect of carbon nanotubes and zinc oxide on electrical and mechanical properties of polyvinyl alcohol matrix composite by electrospinning method. Scientific Reports, 14(1), 1–13. https://doi.org/10.1038/s41598-024-79477-x
Siti Ajizah, F. (2023). Characteristics of PVA/GO Composite Membranes Prepared Using Solution Casting Technique for Reducing Methylene Blue Concentration. Jurnal Ilmu Dan Inovasi Fisika, 7(1), 20–29. https://doi.org/10.24198/jiif.v7i1.40650
Thai, P. T. N., Pham, X. M., Nguyen, T. B., Le, T. M., Viet Tran, C. B., Phong, M. T., & Tran, L. H. (2021). Preparation and characterization of PVA thin-film composite membrane for pervaporation dehydration of ethanol solution. IOP Conference Series: Earth and Environmental Science, 947(1). https://doi.org/10.1088/1755-1315/947/1/012010
Yang, Z., Zhang, M., Xiao, Y., Zhang, X., & Fan, M. (2021). Facile Fabrication of Poly(vinyl alcohol)/Polyquaternium-10 (PVA/PQ-10) Anion Exchange Membrane with Semi-Interpenetrating Network. Macromolecular Materials and Engineering, 306(1), 1–12. https://doi.org/10.1002/mame.202000506
Yee, M. J., Mubarak, N. M., Khalid, M., Abdullah, E. C., & Jagadish, P. (2018). Synthesis of polyvinyl alcohol (PVA) infiltrated MWCNTs buckypaper for strain sensing application. Scientific Reports, 8(1), 1–16. https://doi.org/10.1038/s41598-018-35638-3
Yi, G., Chen, S., Quan, X., Wei, G., Fan, X., & Yu, H. (2018). Enhanced separation performance of carbon nanotube–polyvinyl alcohol composite membranes for emulsified oily wastewater treatment under electrical assistance. Separation and Purification Technology, 197, 107–115. https://doi.org/10.1016/j.seppur.2017.12.058